The Impact of Coagulant Type and Dosage on Turbidity and pH Levels in Raw Water Treatment: A Comparative Study Using The Jar Test Method and Full-Scale Water Treatment Plant
DOI:
https://doi.org/10.22373/ekw.v11i2.30001Keywords:
surface water, water treatment, coagulant, jartest, full scale applicationAbstract
Abstract: The Gajah Mungkur Multipurpose Dam in Wonogiri functions as a source of raw surface water for the surrounding area. This water often contains suspended particles and colloidal substances due to natural processes such as soil erosion, plant decomposition, and microbial activity. This study evaluated three coagulants: Hincolac, PAC 280 Ac, and PAC 250 Ac, at dosages of 60, 70, 80, 90, and 100 ppm. The results of the jar test were compared with those of the full-scale water treatment plant operational test. The findings revealed that the Hincolac coagulant demonstrated superior performance, achieving an efficiency level of 98.60%, which exceeded that of the PAC 250 A and 280 AC coagulants. Hincolac coagulant reached optimal effectiveness at a concentration of 80 ppm, whereas PAC 280 AC and 250 coagulants achieved their highest efficiency at 100 ppm, resulting in turbidity reductions of 98.1% and 97.92%, respectively. Statistical analysis showed that all coagulant types significantly affected turbidity, pH, and floc size (p < 0.001). In a comprehensive application, a dosage of Hincolac 67 ± 7.7 ppm was comparable to the tube test method and effectively achieved a 99% reduction in turbidity in the water-treatment output. Elevated alkalinity and Al₂O₃ concentrations significantly influence the effectiveness of coagulant-based water treatment.
Abstrak: Bendungan Serbaguna Gajah Mungkur di Wonogiri berfungsi sebagai sumber air baku berbasis air permukaan. Air permukaan sering kali mengandung partikel tersuspensi dan bahan koloid yang dihasilkan dari kejadian alami, seperti erosi tanah, pembusukan tanaman, dan aktivitas mikroba. Studi ini melibatkan tiga jenis koagulan, yaitu Hincolac, PAC 280 Ac, dan PAC 250 Ac, dan menggunakan metode dosis variabel, 60, 70, 80, 90, dan 100 (ppm). Hasil uji jar test dibandingkan dengan hasil uji operasional wtp kapasitas penuh. Hasil studi menunjukkan bahwa koagulan Hincolac menunjukkan kinerja yang lebih baik, mencapai tingkat efisiensi yang tinggi sebesar 98,60% lebih baik dari pada koagulan jenis PAC 250 A dan 280 AC. Koagulan Hincolac mencapai efisiensi tertinggi pada konsentrasi 80 ppm, dibandingkan dengan koagulan PAC 280 AC dan 250 yang dicapai pada konsentrasi 100 ppm, menghasilkan pengurangan kekeruhan 98,1% dan 97,92%. Analisis statistik menunjukkan bahwa semua jenis koagulan memiliki dampak yang signifikan terhadap kekeruhan, pH, dan ukuran flok, dengan nilai p <0,001. Dalam aplikasi skala penuh, dosis Hincolac 67 ± 7,7 ppm sebanding dengan metode uji tabung, dan berhasil mencapai pengurangan kekeruhan 99% pada output pengolahan air. Tingkat kebasaan dan konsentrasi Al2O3 yang tinggi memiliki dampak yang signifikan terhadap hasil akhir pengolahan air berbasis koagulan.
References
Adeniyi, A. G., Abdulkareem, S. A., Emenike, E. C., Abdulkareem, M. T., Iwuozor, K. O., Amoloye, M. A., Ahmed, I. I., & Awokunle, O. E. (2022). Development and characterisation of microstructural and mechanical properties of hybrid polystyrene composites filled with kaolin and expanded polyethylene powder. Results in Engineering, 14(March), 100423. https://doi.org/10.1016/j.rineng.2022.100423
Aghyani, R., Nabi Bidhendi, G., Mehrdadi, N., & Amiri, M. J. (2023). Comparative study of Poly Aluminum Ferric and Poly Aluminum Chloride Performance for Turbidity Removal from River Water. Environmental Energy and Economic Research, 7(3), 1–7. https://doi.org/10.22097/eeer.2023.393733.1287
Ardhianto, R., Anggrainy, A. D., Samudro, G., Triyawan, A., & Bagastyo, A. Y. (2024). A study of continuous-flow electrocoagulation process to minimize chemicals dosing in the full-scale treatment of plastic plating industry wastewater. Journal of Water Process Engineering, 60, 105217. https://doi.org/https://doi.org/10.1016/j.jwpe.2024.105217
Bagastyo, A. Y., Nurhayati, E., Manah, S. P. H., Iswari, A. A. W. R., Yulikasari, A., Warmadewanthi, I. D. A. A., & Lin, T.-F. (2023). The role of aeration and pre-chlorination prior to coagulation-flocculation process in water treatment: A laboratory and field research in Indonesia. Case Studies in Chemical and Environmental Engineering, 7, 100352. https://doi.org/https://doi.org/10.1016/j.cscee.2023.100352
Chen, X., Wu, X.-N., Feng, J.-C., Wang, Y., Zhang, X.-C., Lin, Y.-L., Wang, B., & Zhang, S. (2024). Nonlinear differential equations and their application to evaluating the integrated impacts of multiple parameters on the biochemical safety of drinking water. Journal of Environmental Management, 355, 120493. https://doi.org/10.1016/j.jenvman.2024.120493
Chen, Y., Nakazawa, Y., Matsui, Y., Shirasaki, N., & Matsushita, T. (2020). Sulfate ion in raw water affects performance of high-basicity PACl coagulants produced by Al(OH)3 dissolution and base-titration: Removal of SPAC particles by coagulation-flocculation, sedimentation, and sand filtration. Water Research, 183, 116093. https://doi.org/10.1016/j.watres.2020.116093
Cheng, W. P., Chang, J. N., Chen, P. H., Yu, R. F., & Huang, Y. W. (2011). Turbidity fluctuation as a measure of floc size in a coagulation pilot study. Desalination and Water Treatment, 30(1), 1–7. https://doi.org/https://doi.org/10.5004/dwt.2011.1878
Ding, J., Pan, Y., Li, L., Liu, H., Zhang, Q., Gao, G., & Pan, B. (2020). Synergetic adsorption and electrochemical classified recycling of Cr(VI) and dyes in synthetic dyeing wastewater. Chemical Engineering Journal, 384, 123232. https://doi.org/https://doi.org/10.1016/j.cej.2019.123232
Guo, G., Hao, J., Tian, F., Liu, C., Ding, K., Xu, J., Zhou, W., & Guan, Z. (2020). Decolorization and detoxification of azo dye by halo-alkaliphilic bacterial consortium: Systematic investigations of performance, pathway and metagenome. Ecotoxicology and Environmental Safety, 204, 111073. https://doi.org/https://doi.org/10.1016/j.ecoenv.2020.111073
Kementerian Pekerjaan Umum dan Perumahan Rakyat (PUPR). (2021). Report Re-Layout WTP SPAM Regional Wosusokas. Konsultan Implementasi (IC), Proyek SPAM Regional Wosusokas, Indonesia. Kontrak No. 06/PKK/PSPAM/KONS-IC.01/2021.
Hamdan, S., & El-Naas, M. (2014). An electrocoagulation column (ECC) for groundwater purification. Journal of Water Process Engineering, 4, 25–30. https://doi.org/10.1016/j.jwpe.2014.08.004
Jiao, R., Xu, H., Xu, W., Yang, X., & Wang, D. (2015). Influence of coagulation mechanisms on the residual aluminum – The roles of coagulant species and MW of organic matter. Journal of Hazardous Materials, 290, 16–25. https://doi.org/https://doi.org/10.1016/j.jhazmat.2015.02.041
Khan, K., Roy, K., & Benfenati, E. (2019). Ecotoxicological QSAR modeling of endocrine disruptor chemicals. Journal of Hazardous Materials, 369, 707–718. https://doi.org/https://doi.org/10.1016/j.jhazmat.2019.02.019
Lapointe, M., Papineau, I., Peldszus, S., Peleato, N., & Barbeau, B. (2021). Identifying the best coagulant for simultaneous water treatment objectives: Interactions of mononuclear and polynuclear aluminum species with different natural organic matter fractions. Journal of Water Process Engineering, 40, 101829. https://doi.org/10.1016/j.jwpe.2020.101829
Lin, J.-L., & Ika, A. R. (2019). Enhanced Coagulation of Low Turbid Water for Drinking Water Treatment: Dosing Approach on Floc Formation and Residuals Minimization. Environmental Engineering Science, 36(6), 732–738. https://doi.org/10.1089/ees.2018.0430
Pirhashemi, M., Habibi-Yangjeh, A., & Rahim Pouran, S. (2018). Review on the criteria anticipated for the fabrication of highly efficient ZnO-based visible-light-driven photocatalysts. Journal of Industrial and Engineering Chemistry, 62, 1–25. https://doi.org/https://doi.org/10.1016/j.jiec.2018.01.012
Saritha, V., Srinivas, N., & Srikanth Vuppala, N. V. (2017). Analysis and optimization of coagulation and flocculation process. Applied Water Science, 7(1), 451–460. https://doi.org/10.1007/s13201-014-0262-y
Saxena, K., & Brighu, U. (2020). Optimized coagulation of humic acid and mineral turbidity at alkaline pH using high basicity PACl. Water Supply, 20(6), 2324–2338. https://doi.org/10.2166/ws.2020.141
Shammas, N. (2007). Coagulation and Flocculation (pp. 103–139). https://doi.org/10.1385/1-59259-820-x:103
Skaf, D. W., Punzi, V. L., Rolle, J. T., & Kleinberg, K. A. (2020). Removal of micron-sized microplastic particles from simulated drinking water via alum coagulation. Chemical Engineering Journal, 386, 123807. https://doi.org/https://doi.org/10.1016/j.cej.2019.123807
Smotraiev, R., Nehrii, A., Koltsova, E., Anohina, A., Sorochkina, K., & Ratnaweera, H. (2022). Comparison of wastewater coagulation efficiency of pre-polymerised zirconium and traditional aluminium coagulants. Journal of Water Process Engineering, 47(February), 102827. https://doi.org/10.1016/j.jwpe.2022.102827
Wang, D., Wu, J., Deng, L., Li, Z., & Wang, Y. (2021). A real-time optimization control method for coagulation process during drinking water treatment. Nonlinear Dynamics, 105(4), 3271–3283. https://doi.org/10.1007/s11071-021-06794-5
Yang, Z. L., Gao, B. Y., Yue, Q. Y., & Wang, Y. (2010). Effect of pH on the coagulation performance of Al-based coagulants and residual aluminum speciation during the treatment of humic acid–kaolin synthetic water. Journal of Hazardous Materials, 178(1–3), 596–603. https://doi.org/10.1016/j.jhazmat.2010.01.127
Yang, R., Li, H., Huang, M., Yang, H., & Li, A. (2016). A review on chitosan-based flocculants and their applications in water treatment. Water Research, 95, 59–89. https://doi.org/https://doi.org/10.1016/j.watres.2016.02.068
Zhang, Y., Diehl, A., Lewandowski, A., Gopalakrishnan, K., & Baker, T. (2020). Removal efficiency of micro- and nanoplastics (180 nm–125 μm) during drinking water treatment. Science of The Total Environment, 720, 137383. https://doi.org/https://doi.org/10.1016/j.scitotenv.2020.137383
Zhang, Z., Jing, R., He, S., Qian, J., Zhang, K., Ma, G., Chang, X., Zhang, M., & Li, Y. (2018). Coagulation of low temperature and low turbidity water: Adjusting basicity of polyaluminum chloride (PAC) and using chitosan as coagulant aid. Separation and Purification Technology, 206, 131–139. https://doi.org/https://doi.org/10.1016/j.seppur.2018.05.051
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